Crystal structure and Hirshfeld surface analysis of (3a SR,6 RS,6a SR,7 RS,11b SR,11c RS)-2,2-dibenzyl-2,3,6a,11c-tetra-hydro-1 H,6 H,7 H-3a,6:7,11b-di-epoxy-dibenzo[ de, h]isoquinolin-2-ium tri-fluoro-methane-sulfonate

Atioğlu, ZelihaAkkurt, MehmetMammadova, Gunay Z.Mlowe, Sixberth2022-02-152022-02-1520212056-9890https://doi.org/10.1107/S2056989021010173https://hdl.handle.net/20.500.12695/1475TARAMAWOSTARAMAPUBMEDTARAMASCOPUSIn the cation of the title salt, C30H28NO2 + CF3O3S , the four tetrahydrofuran rings adopt envelope conformations. In the crystal, pairs of cations are linked by dimeric C—H O hydrogen bonds, forming two R2 2(6) ring motifs parallel to the (001) plane. The cations and anions are connected by further C—H O hydrogen bonds, forming a three-dimensional network structure. Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H H (47.6%), C H/H C (20.6%), O H/H O (18.0%) and F H/H F (9.9%) interactions.eninfo:eu-repo/semantics/openAccesscrystal structuretetrahydrofuran ringpiperidine ringC—HO hydrogen bondsHirshfeld surface analysisIMDAF reactionDiels–Alder reactionCrystal structure and Hirshfeld surface analysis of (3a SR,6 RS,6a SR,7 RS,11b SR,11c RS)-2,2-dibenzyl-2,3,6a,11c-tetra-hydro-1 H,6 H,7 H-3a,6:7,11b-di-epoxy-dibenzo[ de, h]isoquinolin-2-ium tri-fluoro-methane-sulfonateArticleE7710721077Q3WOS:000718356500003N/A