Sadikhova, Nurlana DAtioğlu, ZelihaGuliyeva, Narmina AShelukho, Evgeniya RPolyanskaya, Darya KKhrustalev, Victor NAkkurt, MehmetBhattarai, Ajaya2024-02-232024-02-232023https://doi.org/10.1107/S2056989023010800https://hdl.handle.net/20.500.12695/2676In the title compound, C20H18N2S, the asymmetric unit comprises two similar molecules (A and B). In molecule A, the central thiophene ring makes dihedral angles of 89.96?(12) and 57.39?(13)° with the 1H-pyrrole rings, which are bent at 83.22?(14)° relative to each other, and makes an angle of 85.98?(11)° with the phenyl ring. In molecule B, the corresponding dihedral angles are 89.49?(13), 54.64?(12)°, 83.62?(14)° and 85.67?(11)°, respectively. In the crystal, molecular pairs are bonded to each other by N—H?N interactions. N—H?? and C—H?? interactions further connect the molecules, forming a three-dimensional network. A Hirshfeld surface analysis indicates that H?H (57.1% for molecule A; 57.3% for molecule B), C?H/H?C (30.7% for molecules A and B) and S?H/H?S (6.2% for molecule A; 6.4% for molecule B) interactions are the most important contributors to the crystal packing.eninfo:eu-repo/semantics/openAccess[Keywords Not Available]Crystal structure and Hirshfeld surface analysis of 3-benzyl-2-[bis(1H-pyrrol-2-yl)methyl]thiopheneArticle8017277