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Öğe Beech (Fagus orientalis) wood modification through the incorporation of polystyrene-ricinoleic acid copolymer with Ag nanoparticles(Springer, 2022) Can, Ahmet; Sivrikaya, Hüseyin; Hazer, Baki; Palanti, SabrinaCellulose is an international journal devoted to the dissemination of research and scientific and technological progress in the field of cellulose and related naturally occurring polymers. The journal is concerned with the pure and applied science of cellulose and related materials, and also with the development of relevant new technologies. This includes the chemistry, biochemistry, physics and materials science of cellulose and its sources, including wood and other biomass resources, and their derivatives. Coverage extends to the conversion of these polymers and resources into manufactured goods, such as pulp, paper, textiles, and manufactured as well natural fibers, and to the chemistry of materials used in their processing. Cellulose publishes review articles, research papers, and technical notes.Öğe Chemical Modification of Poplar Wood with Benzophenone Tetracarboxylic Di Methacrylates(2020) Can, Ahmet; Hazer, Baki; Sivrikaya, HüseyinAim of study: The aim of this study was to analyze the use of benzophenone tetracarboxylic di methacrylates material in wood modification process and the changes in poplar wood. Material and methods: Poplar wood (Populus euramericana) was impregnated with the hydroxyethyl (or glycidyl) methacrylate esters of 3,3,4,4-benzophenone tetracarboxylic dianhydride. The liquid esters were obtained by reaction of BTDA with hydroxy ethyl (BTD-H) (or glycidyl, BTD-G) methacrylate. The wood-BTD-H (and BTD-G) interaction was confirmed by the characteristic signals in Fourier-transform infrared (FT-IR) spectroscopy. The decay resistance and physical behaviour of the modified wood was investigated. Main results: The BDTA-H samples displayed less colour change than the BDTA-G samples. Before decay testing, mini-block samples were leached according to the European Committee for Standardization (EN 84 1997) standard, then control and modified samples were subjected to white-rot fungus (Trametes versicolor). Modification with BTD-G yielded a high improvement in decay resistance (68-72%). Highlights: In the esterification of the chemical, it is benefited only from the sun's rays without the need for high temperature and pressure.Öğe Fungal inhibition and chemical characterization of wood treated with novel polystyrene-soybean oil copolymer containing silver nanoparticles(Elsevier Sci Ltd, 2018) Can, Ahmet; Sivrikaya, Huseyin; Hazer, BakiIn this study, Scots pine (Pinus sylvestris L.) samples were impregnated with autoxidized soybean oil polymer containing Ag nanoparticles (Agsbox) and polystyrene-soybean oil copolymer (AgPSsb) in order to inhibit white rot fungus (Trametes versicolor). Chemical changes of the impregnated specimens were characterized by FTIR techniques. The higher concentration of nano preservative resulted in higher weight percent gain (WPG) in the impregnated samples. The samples impregnated with 1.5% of Agsbox, had the highest WPG (2.98%). The silver nanocomposite-impregnated wood specimens improved the anti-fungal properties. In addition, treatment with 0.4% AgPSsb resulted in the lowest moisture content (23.4%) after decay tests. In the samples, the lowest weight loss (0.87%) due to fungal decay was observed with the use of 0.4 wt% of AgPSsb. Mass losses of Agsbox impregnated specimens at 1.5% and 0.04% were 2.86% and 4.61% respectively. The FTIR spectra of the specimens impregnated with the nanocomposites showed the impregnated components at the peaks of 2910 cm(-1) and 1714 cm(-1) in particular.Öğe Physical, biological and chemical characterisation of wood treated with silver nanoparticles(Springer, 2019) Can, Ahmet; Palanti, Sabrina; Sivrikaya, Huseyin; Stefani, Federico; Hazer, BakiNowadays, environmentally friendly processes are of great interest and are considerably needed due to the environmental pollution seems to be a problem worldwide. For this reason, in this study, silver nanoparticles were synthesized using environmentally-friendly methods and their effectiveness as wood preservatives was investigated. Scots pine (Pinus sylvestris L.) samples were impregnated with an autoxidized soybean oil polymer containing Ag nanoparticles (Agsbox). Samples characterised by Fourier transform infrared spectroscopy (FTIR) were tested against brown rot (Coniophora puteana) and wood-destroying insects (Hylotrupes bajulus). In addition, decay tests were applied to mini-block samples leached according to the EN 84 standard. Results demonstrated that Agsbox increased decay resistance in the unleached samples. However, low efficacy was exhibited against newborn H. bajulus larvae. As a results of FTIR measurement, impregnated with the nanocomposites showed significant changes at the 2910cm(-1) (C-H) and 1712cm(-1) (C=O) peaks.Öğe Thermal behavior and decay performance of wood modified with poly(ethyl cyanoacrylate)(Taylor & Francis, 2021) Can, Ahmet; Sivrikaya, Hüseyin; Hazer, BakiEthyl cyanoacrylate polymerizes at room temperature, and is often used as an adhesive in many areas for a wide variety of applications. In this study, the possibility of using poly(ethyl cyanoacrylate) in the field of wood modification was investigated. For this purpose, Scots pine (Pinus sylvestris L.) and Oriental beech (Fagus orientalis) samples were impregnated with poly(ethyl cyanoacrylate) that was synthesized using acetone. Modified samples were characterized by Thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), and Scanning Electron Microscopy (ESEM). Decay performance was done with white rot fungus (Trametes versicolor (L: Fr.) Pilat. (FFPRI 1030)) for beech wood and brown rot fungus Coniophera puteana for pine wood; the European standard EN113 FTIR analysis indicated that PECA could appreciably alter the chemical structure in modified wood. Thermal changes in modified wood were be minor compared to those of untreated wood. Samples treated with PECA had significantly lower mass losses than untreated samples as a result of fungal exposure to Coniophora puteana and T. versicolor.