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Öğe Fungal inhibition and chemical characterization of wood treated with novel polystyrene-soybean oil copolymer containing silver nanoparticles(Elsevier Sci Ltd, 2018) Can, Ahmet; Sivrikaya, Huseyin; Hazer, BakiIn this study, Scots pine (Pinus sylvestris L.) samples were impregnated with autoxidized soybean oil polymer containing Ag nanoparticles (Agsbox) and polystyrene-soybean oil copolymer (AgPSsb) in order to inhibit white rot fungus (Trametes versicolor). Chemical changes of the impregnated specimens were characterized by FTIR techniques. The higher concentration of nano preservative resulted in higher weight percent gain (WPG) in the impregnated samples. The samples impregnated with 1.5% of Agsbox, had the highest WPG (2.98%). The silver nanocomposite-impregnated wood specimens improved the anti-fungal properties. In addition, treatment with 0.4% AgPSsb resulted in the lowest moisture content (23.4%) after decay tests. In the samples, the lowest weight loss (0.87%) due to fungal decay was observed with the use of 0.4 wt% of AgPSsb. Mass losses of Agsbox impregnated specimens at 1.5% and 0.04% were 2.86% and 4.61% respectively. The FTIR spectra of the specimens impregnated with the nanocomposites showed the impregnated components at the peaks of 2910 cm(-1) and 1714 cm(-1) in particular.Öğe Physical, biological and chemical characterisation of wood treated with silver nanoparticles(Springer, 2019) Can, Ahmet; Palanti, Sabrina; Sivrikaya, Huseyin; Stefani, Federico; Hazer, BakiNowadays, environmentally friendly processes are of great interest and are considerably needed due to the environmental pollution seems to be a problem worldwide. For this reason, in this study, silver nanoparticles were synthesized using environmentally-friendly methods and their effectiveness as wood preservatives was investigated. Scots pine (Pinus sylvestris L.) samples were impregnated with an autoxidized soybean oil polymer containing Ag nanoparticles (Agsbox). Samples characterised by Fourier transform infrared spectroscopy (FTIR) were tested against brown rot (Coniophora puteana) and wood-destroying insects (Hylotrupes bajulus). In addition, decay tests were applied to mini-block samples leached according to the EN 84 standard. Results demonstrated that Agsbox increased decay resistance in the unleached samples. However, low efficacy was exhibited against newborn H. bajulus larvae. As a results of FTIR measurement, impregnated with the nanocomposites showed significant changes at the 2910cm(-1) (C-H) and 1712cm(-1) (C=O) peaks.