Crystal structure and Hirshfeld surface analysis of ethane-1,2-diaminium 3-[2-(1,3-dioxo-1,3-diphenylpropan-2-ylidene)hydrazinyl]-5-nitro-2-oxidobenzenesulfonate dihydrate
Yükleniyor...
Dosyalar
Tarih
2018
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
Attribution-NonCommercial-ShareAlike 4.0 International
info:eu-repo/semantics/openAccess
info:eu-repo/semantics/openAccess
Özet
In the anion of the title hydrated salt, C2H10N22+·C21H13N3O8S2?·2H2O, the planes of the phenyl rings and the benzene ring of the 5-nitro-2-oxidobenzenesulfonate group are inclined to one another by 44.42?(11), 56.87?(11) and 77.70?(12)°. In the crystal, the anions are linked to the cations and the water molecules by N—H...O and O—H...O hydrogen bonds, forming a three-dimensional network. Furthermore, there are face-to-face ?–? stacking interactions between the centroids of one phenyl ring and the benzene ring of the 5-nitro-2-oxidobenzenesulfonate group [centroid–centroid distance = 3.8382?(13)?Å and slippage = 1.841?Å]. A Hirshfeld surface analysis was conducted to verify the contributions of the different intermolecular interactions.
Açıklama
TARAMAPUBMED
TARAMASCOPUS
TARAMAWOS
TARAMASCOPUS
TARAMAWOS
Anahtar Kelimeler
Crystal structure, 5-nitro-2-oxidobenzenesulfonate group, Hydrogen bond, ?–? stacking, Hirshfeld surface analysis
Kaynak
Acta Crystallographica Section E: Crystallographic Communications
WoS Q Değeri
N/A
Scopus Q Değeri
Q3
Cilt
74
Sayı
7
Künye
ATİOĞLU, Z., AKKURT, M., Toze, F. A. A., Huseynov, F. E., & Hajiyeva, S. F. (2018). Crystal structure and Hirshfeld surface analysis of ethane 1 2 diaminium 3 2 1 3 dioxo 1 3 di phenyl propan 2 yl idene hydrazin yl 5 nitro 2 oxido benzene sulfonate dihydrate. Acta Crystallographica Section E, 74(7), 1021–1025.
