Crystal structure and Hirshfeld surface analysis of (3a SR,6 RS,6a SR,7 RS,11b SR,11c RS)-2,2-dibenzyl-2,3,6a,11c-tetra-hydro-1 H,6 H,7 H-3a,6:7,11b-di-epoxy-dibenzo[ de, h]isoquinolin-2-ium tri-fluoro-methane-sulfonate
Yükleniyor...
Dosyalar
Tarih
2021
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
In the cation of the title salt, C30H28NO2 + CF3O3S , the four tetrahydrofuran rings adopt envelope conformations. In the crystal, pairs of cations are linked by dimeric C—H O hydrogen bonds, forming two R2 2(6) ring motifs parallel to the (001) plane. The cations and anions are connected by further C—H O hydrogen bonds, forming a three-dimensional network structure. Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H H (47.6%), C H/H C (20.6%), O H/H O (18.0%) and F H/H F (9.9%) interactions.
Açıklama
TARAMAWOS
TARAMAPUBMED
TARAMASCOPUS
TARAMAPUBMED
TARAMASCOPUS
Anahtar Kelimeler
crystal structure, tetrahydrofuran ring, piperidine ring, C—HO hydrogen bonds, Hirshfeld surface analysis, IMDAF reaction, Diels–Alder reaction
Kaynak
Acta Cryst
WoS Q Değeri
N/A
Scopus Q Değeri
Q3
Cilt
Sayı
E77
