Crystal structure and Hirshfeld surface analysis of (E)-4-({2,2-di­chloro-1-[4-(di­methyl­amino)­phen­yl]ethenyl}diazen­yl)benzo­nitrile

Küçük Resim

Dosyalar

vm2253.pdf (1.04 MB)

Tarih

2021

Yazarlar

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Erişim Hakkı

info:eu-repo/semantics/openAccess

Özet

In the title compound, C17H14Cl2N4, the dihedral angle between the aromatic rings is 50.09?(9)°. The central –N=N– unit shows an E configuration. In the crystal, C—H?N inter­actions, C—Cl?? and ?–? stacking inter­actions [centroid-to-centroid distance = 3.7719?(14)?Å] link the mol­ecules, forming mol­ecular layers approximately parallel to the (002) plane. Additional weak van der Waals inter­actions between the layers consolidate the three-dimensional packing. Hirshfeld surface analysis indicates that the most important contributions for the crystal packing are from H?H (33.6%), N?H/ H?N (17.2%), Cl?H/H?Cl (14.1%) and C?H/H?C (14.1%) contacts.

Açıklama

TARAMAWOS
TARAMAPUBMED
TARAMASCOPUS

Anahtar Kelimeler

crystal structure, C—HN interactions, C—Cl interactions, – stacking interactions, Hirshfeld surface analysis

Kaynak

WoS Q Değeri

N/A

Scopus Q Değeri

Q3

Cilt

E77

Sayı

Künye

Bağlantı

https://doi.org/10.1107/S2056989021009154
 https://hdl.handle.net/20.500.12695/1505

Koleksiyon

HEE - Makale Koleksiyonu