Crystal structure and Hirshfeld surface analysis of (3aR, 4S, 7S, 7aS)-4, 5, 6, 7, 8, 8-hexachloro-2-{6-[(3aR, 4R, 7R, 7aS)-4, 5, 6, 7, 8, 8-hexachloro-1, 3-dioxo-1, 3, 3a, 4 …
Yükleniyor...
Dosyalar
Tarih
2021
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
The molecule of the title compound, C24H16Cl12N2O4, is generated by a crystallographic inversion centre at the midpoint of the central C—C bond. A kink in the molecule is defined by a torsion angle of ?169.86?(15)° about this central bond of the alkyl bridge. The pyrrolidine ring is essentially planar [max. deviation = 0.014?(1)?Å]. The cyclohexane ring has a boat conformation, while both cyclopentane rings adopt an envelope conformation. In the crystal structure, molecules are linked by intermolecular C—H?O, C—H?Cl and C—Cl?? interactions, and short intermolecular Cl?O and Cl?Cl contacts, forming a three-dimensional network.
Açıklama
TARAMAWOS
TARAMAPUBMED
TARAMASCOPUS
TARAMAPUBMED
TARAMASCOPUS
Anahtar Kelimeler
Crystal structure, Pyrrolidine ring, Cyclopentane ring, Cyclohexane ring, Hirshfeld surface analysis
Kaynak
Acta Cryst
WoS Q Değeri
N/A
Scopus Q Değeri
Q3
Cilt
Sayı
E77
