Synthesis, crystal structure and Hirshfeld surface analysis of (2Z,2?E)-2,2?-(3-meth­­oxy-3-phenylpropane-1,2-diyl­­idene)bis­­(hydrazine-1-carbo­thio­amide) di­methyl­formamide monosolvate

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dc.contributor.authorGuseinov, Firudin I
dc.contributor.authorKnyazev, Aleksandr V
dc.contributor.authorShuvalova, Elena V
dc.contributor.authorKobrakov, Konstantin I
dc.contributor.authorSamigullina, Aida I
dc.contributor.authorAtioğlu, Zeliha
dc.contributor.authorAkkurt, Mehmet
dc.contributor.authorBhattarai, Ajaya
dc.date.accessioned2024-02-23T08:44:55Z
dc.date.available2024-02-23T08:44:55Z
dc.date.issued2023en_US
dc.departmentKapadokya Üniversitesi, Uygulamalı Bilimler Yüksekokulu, Havacılık Elektrik ve Elektroniği Bölümü
dc.description.abstractThe overall molecular configuration of the title compound, C12H16N6OS2·C3H7NO, is stabilized in the solid state by intramolecular C—H?N, C—H?O, N—H?N and N—H?O interactions, forming S(5) ring motifs. In the crystal, molecules are linked to each other and solvent dimethylformamide molecules by N—H?S, N—H?O, C—H?O and C—H?S hydrogen bonds, forming a three dimensional network. The phenyl ring of the title compound is disordered over two sites with an occupancy ratio of 0.57?(4):0.43?(4). A Hirshfeld surface analysis was performed to quantify the contributions of the different intermolecular interactions, indicating that the most important contributions to the crystal packing are from H?H (38.7%), S?H / H?S (24.0%), C?H / H?C (18.5%) and N?H / H?N (9.8%) interactions.
dc.identifier.endpage915en_US
dc.identifier.issue10en_US
dc.identifier.startpage910en_US
dc.identifier.urihttps://doi.org/10.1107/S2056989023007946
dc.identifier.urihttps://hdl.handle.net/20.500.12695/2673
dc.identifier.volume79en_US
dc.institutionauthorAtioğlu, Zeliha
dc.language.isoen
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectcrystal structure
dc.subjectdisorder
dc.subjecthydrogen bonds
dc.subjectHirshfeld surface analysis
dc.subject?-chloro­ketone
dc.subjectchloro­oxirane
dc.subjectbis­thio­semi­carbazone
dc.titleSynthesis, crystal structure and Hirshfeld surface analysis of (2Z,2?E)-2,2?-(3-meth­­oxy-3-phenylpropane-1,2-diyl­­idene)bis­­(hydrazine-1-carbo­thio­amide) di­methyl­formamide monosolvate
dc.typeArticle

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