Synthesis and characterization of comb-type graft copolymers by redox polymerization and "click" chemistry method

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dc.contributor.authorSavas, Bedrettin
dc.contributor.authorOzturk, Temel
dc.contributor.authorMeyvaci, Ergul
dc.contributor.authorHazer, Baki
dc.date.accessioned2020-05-21T01:27:37Z
dc.date.available2020-05-21T01:27:37Z
dc.date.issued2020
dc.departmentKapadokya Üniversitesi, Uygulamalı Bilimler Yüksekokulu, Havacılık Yönetimi Bölümü
dc.descriptionTARAMAWOS
dc.descriptionTARAMASCOPUS
dc.description.abstractThe synthesis of poly(epichlorohydrin- g-methyl methacrylate) [poly(ECH-g-MMA)] comb-type graft copolymers were carried out by use of a "click" chemistry to graft terminally propargyl poly(methyl methacrylate) (PMMA-propargyl) to poly(epichlorohydrin) azido (PECH-N-3). For this purpose, PECH-N-3 was synthesized by using poly(epichlorohydrin) and sodium azide. PMMA-propargyl was obtained by reaction of methyl methacrylate and propargyl alcohol via redox polymerization technique. By using PECH-N-3 and PMMA-propargyl, the comb-type graft copolymers were obtained. Characterization of the modified homopolymers and the comb-type graft copolymers was performed by using FT-IR, H-1-NMR, SEM, GPC, and elemental analysis techniques. Thermal transitions and degradation features of the comb-type graft copolymers were investigated by using DSC and TGA methods. Spectroscopic and thermal analyses revealed that both group modifications and coupling reactions were successfully achieved.
dc.description.sponsorshipKafkas University Scientific Research Fund [2018-FM-77]
dc.description.sponsorshipThe work was founded by Kafkas University Scientific Research Fund (Grand Number: 2018-FM-77).
dc.identifier.doi10.1007/s42452-020-1985-z
dc.identifier.issn2523-3963
dc.identifier.issn2523-3971
dc.identifier.issue2en_US
dc.identifier.scopusqualityN/A
dc.identifier.urihttps://doi.org/10.1007/s42452-020-1985-z
dc.identifier.urihttps://hdl.handle.net/20.500.12695/39
dc.identifier.volume2en_US
dc.identifier.wosWOS:000517964300042
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer International Publishing Ag
dc.relation.ispartofSn Applied Sciences
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject"Click" chemistry
dc.subjectRedox polymerization
dc.subjectComb-type graft copolymer
dc.subjectPoly(epichlorohydrin)
dc.subjectPoly(methyl methacrylate)
dc.titleSynthesis and characterization of comb-type graft copolymers by redox polymerization and "click" chemistry method
dc.typeArticle

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