Crystal structure and Hirshfeld surface analysis of dimethyl (3aS,6R,6aS,7S)-2-(2,2,2-trifluoroacetyl)-2,3-dihydro-1H,6H,7H-3a,6:7,9a-diepoxybenzo[de]isoquinoline-3a1,6a-dicarboxylate
Yükleniyor...
Tarih
2018
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
Attribution-NonCommercial-ShareAlike 4.0 International
info:eu-repo/semantics/openAccess
info:eu-repo/semantics/openAccess
Özet
The title molecule, C18H16F3NO7, comprises a fused cyclic system containing four five membered (two dihydrofuran and two tetrahydrofuran) rings and one six-membered (piperidine) ring. The five-membered dihydrofuran and tetrahydrofuran rings adopt envelope conformations, and the six-membered piperidine ring adopts a distorted chair conformation. Intramolecular OF interactions help to stabilize the conformational arrangement. In the crystal structure, molecules are linked by weak C—HO and C—HF hydrogen bonds, forming a three dimensional network. The Hirshfeld surface analysis confirms the dominant role of HH contacts in establishing the packing
Açıklama
TARAMAPUBMED
TARAMASCOPUS
TARAMAWOS
TARAMASCOPUS
TARAMAWOS
Anahtar Kelimeler
Crystal structure, Dihydrofuran ring, Tetrahydrofuran ring, Fused hexacyclic system, Piperidine ring, Hiershfeld surface analysis
Kaynak
Acta Crystallographica Section E: Crystallographic Communications
WoS Q Değeri
N/A
Scopus Q Değeri
Q3
Cilt
74
Sayı
11
Künye
ATİOĞLU, Z., AKKURT, M., Toze, F. A. A., Dorovatovskii, P. V., Guliyeva, N. A., & Panahova, H. M. (2018). Crystal structure and Hirshfeld surface analysis of dimethyl 3aS 6R 6aS 7S 2 2 2 2 tri fluoro acet yl 2 3 di hydro 1H 6H 7H 3a 6 7 9a di epoxy benzo de iso quinoline 3a1 6a di carboxyl ate. Acta Crystallographica Section E, 74(11), 1599–1604.
