Crystal structures of di-bromido-{ N-[(pyridin-2-yl-? N)methyl-idene]picolinohydrazide-? 2N', O}cadmium methanol monosolvate and di-iodido{ N-[(pyridin-2-yl-? N)methyl-idene]picolinohydrazide-? 2N', O}cadmium

Basit Öğe Kaydı
dc.contributor.authorKhandar, Ali Akbar
dc.contributor.authorAfkhami, Farhad Akbari
dc.contributor.authorKrautscheid, Harald
dc.contributor.authorKristoffersen, Kenneth Aase
dc.contributor.authorAtioğlu, Zeliha
dc.contributor.authorAkkurt, Mehmet
dc.contributor.authorGörbitz, Carl Henrik
dc.date.accessioned2022-03-22T09:09:22Z
dc.date.available2022-03-22T09:09:22Z
dc.date.issued2017en_US
dc.departmentKapadokya Üniversitesi, Uygulamalı Bilimler Yüksekokulu, Havacılık Elektrik ve Elektroniği Bölümü
dc.descriptionTARAMAPUBMED
dc.description.abstractThe title compounds, [CdBr2(C12H10N4O)]·CH3OH, (I), and [CdI2(C12H10N4O)], (II), are cadmium bromide and cadmium iodide complexes of the ligand (E)-N'-(pyridin-2-yl-methyl-ene)picolinohydrazide. Complex (I) crystallizes as the methanol monosolvate. In both compounds, the Cd2+ cation is ligated by one O atom and two N atoms of the tridentate ligand, and by two bromide anions forming a Br2N2O penta-coordination sphere for (I), and by two iodide anions forming an I2N2O penta-coordination sphere for (II), both with a distorted square-pyramidal geometry. In the crystal of complex (I), mol-ecules are linked by pairs of N-H?O and O-H?Br hydrogen bonds, involving the solvent mol-ecule, forming dimeric units, which are linked by C-H?Br hydrogen bonds forming layers parallel to (101). In the crystal of complex (II), mol-ecules are linked by N-H?I hydrogen bonds, forming chains propagating along [010]. In complex (II), measured at room temperature, the two iodide anions are each disordered over two sites; the refined occupancy ratio is 0.75 (2):0.25 (2).
dc.identifier.endpage701en_US
dc.identifier.startpage698en_US
dc.identifier.urihttps://doi.org/10.1107/S2056989017005308
dc.identifier.urihttps://hdl.handle.net/20.500.12695/1555
dc.identifier.volume73en_US
dc.indekslendigikaynakPubMed
dc.institutionauthorAtioğlu, Zeliha
dc.language.isoen
dc.relation.ispartofActa Cryst
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectbromide
dc.subjectcadmium
dc.subjectcrystal structure
dc.subjecthydrazone
dc.subjecttridentate ligand
dc.subjecthydrogen bonding
dc.subjectiodide
dc.titleCrystal structures of di-bromido-{ N-[(pyridin-2-yl-? N)methyl-idene]picolinohydrazide-? 2N', O}cadmium methanol monosolvate and di-iodido{ N-[(pyridin-2-yl-? N)methyl-idene]picolinohydrazide-? 2N', O}cadmium
dc.typeArticle

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Küçük Resim
İsim:
su5361.pdf
Boyut:
586.75 KB
Biçim:
Adobe Portable Document Format
Açıklama:
Makale / Article
İndir
Lisans paketi
Listeleniyor 1 - 1 / 1
[ X ]
İsim:
license.txt
Boyut:
1.44 KB
Biçim:
Item-specific license agreed upon to submission
Açıklama:
İndir

Koleksiyon

HEE - Makale Koleksiyonu