Synthesis of block/graft copolymers based on vinyl benzyl chloride via reversible addition fragmentation chain transfer (RAFT) polymerization using the carboxylic acid functionalized Trithiocarbonate

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dc.contributor.authorHazer, Baki
dc.contributor.authorArslan, Hulya
dc.contributor.authorSenemoğlu, Yetkin
dc.contributor.authorSen, Şadi
dc.date.accessioned2020-05-21T01:27:38Z
dc.date.available2020-05-21T01:27:38Z
dc.date.issued2019
dc.departmentKapadokya Üniversitesi
dc.descriptionHazer, Baki/0000-0001-8770-805X
dc.descriptionTARAMASCOPUS
dc.descriptionTARAMAWOS
dc.description.abstractReversible Addition-Fragmentation Chain-Transfer (RAFT) polymerization of styrene (St), vinyl benzyl chloride (vbc), tert-butyl methacrylate (tertBMA) and n-butyl methacrylate (nBMA) was investigated using carboxylic acid functionalized trithiocarbonate (R2). A series of random copolymer of styrene and vinyl benzyl chloride was prepared in order to control chloromethyl functionality in the copolymer, via RAFT polymerization. Addition to this, first-order kinetic behavior of the RAFT polymerization of vbc using R2 was also evaluated. A novel series of amphiphilic copolymers based on polyethylene glycol (PEG) with molar masses of 500 and 2000g/mol, functionalized polyvinyl benzyl chloride (Pvbc) were obtained via the Williamson-ether-synthesis. As chloromethyl functionality increases, the introduced PEG increases. Fractional precipitation, thermal properties and water uptakes of the amphiphilic polymer samples were evaluated. The new polymers can be the promising materials with high aqueous solubility capacity.
dc.description.sponsorshipBulent Ecevit University Research Funds [BEU-2017-72118496-01]; Kapadokya University [KUN.2018-BAGP-001]
dc.description.sponsorshipThis work was supported by the Bulent Ecevit University Research Funds (#BEU-2017-72118496-01) and Kapadokya University KUN.2018-BAGP-001. This paper has been proofread by Bulent Ecevit University Article Proofreading and Editing Office.
dc.identifier.doi10.1007/s10965-019-1763-z
dc.identifier.issn1022-9760
dc.identifier.issn1572-8935
dc.identifier.issue5en_US
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1007/s10965-019-1763-z
dc.identifier.urihttps://hdl.handle.net/20.500.12695/42
dc.identifier.volume26en_US
dc.identifier.wosWOS:000463224600001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Sceince
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal Of Polymer Research
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsAttribution-NonCommercial-ShareAlike 4.0 International
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.rights.urihttps://creativecommons.org/licenses/by-nc-sa/4.0/
dc.subjectRAFT polymerization
dc.subjectVinyl benzyl chloride
dc.subjectComb type graft copolymer
dc.subjectBlock copolymer
dc.subjectPolyethylene glycol
dc.subjectnButyl methacrylate
dc.subjectTertButyl methacrylate
dc.titleSynthesis of block/graft copolymers based on vinyl benzyl chloride via reversible addition fragmentation chain transfer (RAFT) polymerization using the carboxylic acid functionalized Trithiocarbonate
dc.typeArticle

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