Synthesisof Biobased Block Copolymers Using A Novel Methacrylated Methyl Salicylate and Poly (3-Hydroxybutyrate)

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dc.contributor.authorHazer, Baki
dc.contributor.authorSubramaniyan, Sathiyaraj
dc.contributor.authorZhang, Baozhong
dc.date.accessioned2022-03-08T07:20:52Z
dc.date.available2022-03-08T07:20:52Z
dc.date.issued2022en_US
dc.departmentKapadokya Üniversitesi, Uygulamalı Bilimler Yüksekokulu, Uçak Gövde ve Motor Bakımı Bölümü
dc.descriptionTARAMAWOS
dc.descriptionTARAMASCOPUS
dc.description.abstractA novel biobased vinyl monomer was synthesized by the reaction of methyl salicylate with methacrylic anhydride. The resulting salicylate based monomer was polymerized by reversible addition fragmentation transfer(RAFT) polymerizations using two or three trithiocarbonate functionalizedpoly(3-hydroxybutyrate) macroagents. The molecular structures of the obtained polymers were confirmed by NMR spectroscopyand GPC analysis.The resulting block copolymers showed glass transition temperature (Tg) at 5°C and melting temperature (Tm) at 160°C according to DSCresults .Compared to PHB, the obtained block copolymers displayed enhanced thermal stabil-ity according to TGA results.
dc.identifier.doi10.1002/slct.202102977
dc.identifier.endpage12265en_US
dc.identifier.issn2365-6549
dc.identifier.issue43en_US
dc.identifier.scopusqualityQ3
dc.identifier.startpage12255en_US
dc.identifier.urihttps://doi.org/10.1002/slct.202102977
dc.identifier.urihttps://hdl.handle.net/20.500.12695/1517
dc.identifier.volume6en_US
dc.identifier.wosWOS:000720942400045
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Sceince
dc.indekslendigikaynakScopus
dc.institutionauthorHazer, Baki
dc.language.isoen
dc.publisherChemistry Europe
dc.relation.ispartofChemistrySelect
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBlock copolymers
dc.subjectKinetics
dc.subjectNaturalproducts
dc.subjectPolymerization
dc.subjectTotalsynthesis
dc.titleSynthesisof Biobased Block Copolymers Using A Novel Methacrylated Methyl Salicylate and Poly (3-Hydroxybutyrate)
dc.typeArticle

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