Synthesis and characterization of poly(-caprolactone-co-ethylene glycol) star-type amphiphilic copolymers by "click" chemistry and ring-opening polymerization

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dc.contributor.authorOzturk, Temel
dc.contributor.authorKılıçlıoğlu, Ali
dc.contributor.authorSavas, Bedrettin
dc.contributor.authorHazer, Baki
dc.date.accessioned2020-05-21T01:27:37Z
dc.date.available2020-05-21T01:27:37Z
dc.date.issued2018
dc.departmentKapadokya Üniversitesi
dc.descriptionTARAMASCOPUS
dc.descriptionTARAMAWOS
dc.description.abstractThe synthesis of poly(-caprolactone-co-ethylene glycol) AAB star-type amphiphilic copolymers were carried out by use of a click chemistry reaction to block propargyl polyethylene glycol (propargyl-PEG) to terminally azide poly(-caprolactone) (PCL-N-3). For this purpose, propargyl-PEG was synthesized by the reaction of PEGs (3000Da, 2000Da, 1500Da, and 1000Da) and propargyl chloride. Terminally chloride poly(-caprolactone) (PCL-Cl) was carried out by means of ring-opening polymerization (ROP) of -caprolactone (CL) and 3-chloro-1,2-propanediol. Synthesis of PCL-N-3 was obtained by the chemical interaction of PCL-Cl and sodium azide. By reacting propargyl-PEG and PCL-N-3, the star-type amphiphilic copolymers were obtained. The characterization of products was accomplished by using multiple instruments including H-1-NMR, FT-IR, GPC, TGA, contact angles, and elemental analysis techniques.
dc.identifier.doi10.1080/10601325.2018.1481344
dc.identifier.endpage594en_US
dc.identifier.issn1060-1325
dc.identifier.issn1520-5738
dc.identifier.issue8en_US
dc.identifier.scopusqualityQ2
dc.identifier.startpage588en_US
dc.identifier.urihttps://doi.org/10.1080/10601325.2018.1481344
dc.identifier.urihttps://hdl.handle.net/20.500.12695/40
dc.identifier.volume55en_US
dc.identifier.wosWOS:000456313400002
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Inc
dc.relation.ispartofJournal Of Macromolecular Science Part A-Pure And Applied Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsAttribution-NonCommercial-ShareAlike 4.0 International
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.rights.urihttps://creativecommons.org/licenses/by-nc-sa/4.0/
dc.subject"Click" chemistry
dc.subjectring-opening polymerization
dc.subjectstar-type amphiphilic copolymer
dc.subjectterminally azide poly(-caprolactone)
dc.subjectpropargyl polyethylene glycol
dc.titleSynthesis and characterization of poly(-caprolactone-co-ethylene glycol) star-type amphiphilic copolymers by "click" chemistry and ring-opening polymerization
dc.typeArticle

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