Crystal structure and Hirshfeld surface analysis of 2,2,2-trichloro-N,N-bis{[(1RS,4SR)-1,4-dihydro-1,4-epoxynaphthalen-1-yl]methyl}acetamide
Yükleniyor...
Dosyalar
Tarih
2021
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
In the title compound, C24H18Cl3NO3, the tetrahydrofuran rings adopt envelope conformations. In the crystal, C-H center dot center dot center dot O hydrogen bonds connect molecules, generating layers parallel to the (001) plane. These layers are connected along the c-axis direction by C-H center dot center dot center dot pi interactions. The packing is further stabilized by interlayer van der Waals and interhalogen interactions. The most important contributions to the surface contacts are from H center dot center dot center dot H (36.8%), Cl center dot center dot center dot H/H center dot center dot center dot Cl (26.6%), C center dot center dot center dot H/H center dot center dot center dot C (18.8%) and O center dot center dot center dot H/H center dot center dot center dot O (11.3%) interactions, as concluded from a Hirshfeld surface analysis.
Açıklama
TARAMAWOS
TARAMAPUBMED
TARAMASCOPUS
TARAMAPUBMED
TARAMASCOPUS
Anahtar Kelimeler
crystal structure, tetrahydrofuran rings, C—HO hydrogen bonds, C—H interactions, Hirshfeld surface analysis, IMDAF reaction, Diels–Alder reaction
Kaynak
Acta Cryst
WoS Q Değeri
N/A
Scopus Q Değeri
N/A
Cilt
77
Sayı
10
