Crystal structure and Hirshfeld surface analysis of diiodido(N '-[(E)-(phenyl)(pyridin-2-yl-kappa N)methyl-idene]pyridine-2-carbohydrazide-kappa N-2 ',O}-cadmium(II)
Yükleniyor...
Tarih
2019
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
Attribution-NonCommercial-ShareAlike 4.0 International
info:eu-repo/semantics/openAccess
info:eu-repo/semantics/openAccess
Özet
In each of the two independent molecules in the asymmetric unit of the title compound, [CdI2(C18H14N4O)], the N,O,N?-tridentate N?-[(E)-(phenyl)(pyridin-2-yl-?N)methylidene]pyridine-2-carbohydrazide ligand and two iodide anions form an I2N2O pentacoordination sphere, with a distorted square-pyramidal geometry, with an I atom in the apical position. Both molecules feature an intramolecular N—H?N hydrogen bond. In the crystal, weak aromatic ?–? stacking interactions [centroid–centroid separation = 3.830?(2)?Å] link the molecules into dimers.
Açıklama
TARAMAPUBMED
TARAMASCOPUS
TARAMAWOS
TARAMASCOPUS
TARAMAWOS
Anahtar Kelimeler
Crystal structure, N0-[(E)-(pyridin-2- yl)methylidene]pyridine-2-carbohydrazide, Cadmium, Odide, Hydrogen bonding, Hirshfeld surface analysis
Kaynak
Acta Crystallographica Section E: Crystallographic Communications
WoS Q Değeri
N/A
Scopus Q Değeri
Q3
Cilt
75
Sayı
7
Künye
ATİOĞLU, Z., Afkhami, F. A., AKKURT, M., Khandar, A. A., & Lazarte, D. C. (2019). Crystal structure and Hirshfeld surface analysis of di iodido N E phen yl pyridin 2 yl ?N methylidene pyridine 2 carbohydrazide ?2N O cadmium II . Acta Crystallographica Section E - CRYSTALLOGRAPHIC COMMUNICATIONS, 75(7), 1061–1064.
