Crystal structure of bis-{ N'-[( E)-4-hy-droxy-benzyl-idene]pyridine-4-carbohydrazide-? N1}di-iodidocadmium methanol disolvate
| dc.contributor.author | Afkhami, Farhad Akbari | |
| dc.contributor.author | Krautscheid, Harald | |
| dc.contributor.author | Atioğlu, Zeliha | |
| dc.contributor.author | Akkurt, Mehmet | |
| dc.date.accessioned | 2022-03-22T09:09:11Z | |
| dc.date.available | 2022-03-22T09:09:11Z | |
| dc.date.issued | 2017 | en_US |
| dc.department | Kapadokya Üniversitesi, Uygulamalı Bilimler Yüksekokulu, Havacılık Elektrik ve Elektroniği Bölümü | |
| dc.description | TARAMAPUBMED | |
| dc.description.abstract | In the title compound, [Cd(C13H11IN3O2)2]·2CH3OH, which crystallizes with Z = 4 in the space group Pbcn, the CdII atom is located on a twofold rotation axis and coordinated by two I- anions and two N atoms from the pyridine rings of the two N'-[(E)-4-hy-droxy-benzyl-idene]pyridine-4-carbohydrazide ligands. The geometry around the CdII atom is distorted tetra-hedral, with bond angles in the range 94.92 (11)-124.29 (2)°. The iodide anions undergo inter-molecular hydrogen-bonding contacts with the C-H groups of the organic ligands of an adjacent complex mol-ecule, generating a chain structure along the b axis. Furthermore, an extensive series of O-H?O, N-H?O and C-H?O hydrogen-bonding inter-actions involving both the complex mol-ecules and the ethanol solvate mol-ecules generate a three-dimensional network. | |
| dc.identifier.endpage | 30 | en_US |
| dc.identifier.startpage | 28 | en_US |
| dc.identifier.uri | https://doi.org/10.1107/S2056989016019575 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12695/1554 | |
| dc.identifier.volume | 73 | en_US |
| dc.indekslendigikaynak | PubMed | |
| dc.institutionauthor | Atioğlu, Zeliha | |
| dc.language.iso | en | |
| dc.relation.ispartof | Acta Cryst | |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | cadmium | |
| dc.subject | crystal structure | |
| dc.subject | hydrazone-based ligand | |
| dc.subject | hydrogen bonding | |
| dc.title | Crystal structure of bis-{ N'-[( E)-4-hy-droxy-benzyl-idene]pyridine-4-carbohydrazide-? N1}di-iodidocadmium methanol disolvate | |
| dc.type | Article |
