Crystal structure of bis-{ N'-[( E)-4-hy-droxy-benzyl-idene]pyridine-4-carbohydrazide-? N1}di-iodidocadmium methanol disolvate

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dc.contributor.authorAfkhami, Farhad Akbari
dc.contributor.authorKrautscheid, Harald
dc.contributor.authorAtioğlu, Zeliha
dc.contributor.authorAkkurt, Mehmet
dc.date.accessioned2022-03-22T09:09:11Z
dc.date.available2022-03-22T09:09:11Z
dc.date.issued2017en_US
dc.departmentKapadokya Üniversitesi, Uygulamalı Bilimler Yüksekokulu, Havacılık Elektrik ve Elektroniği Bölümü
dc.descriptionTARAMAPUBMED
dc.description.abstractIn the title compound, [Cd(C13H11IN3O2)2]·2CH3OH, which crystallizes with Z = 4 in the space group Pbcn, the CdII atom is located on a twofold rotation axis and coordinated by two I- anions and two N atoms from the pyridine rings of the two N'-[(E)-4-hy-droxy-benzyl-idene]pyridine-4-carbohydrazide ligands. The geometry around the CdII atom is distorted tetra-hedral, with bond angles in the range 94.92 (11)-124.29 (2)°. The iodide anions undergo inter-molecular hydrogen-bonding contacts with the C-H groups of the organic ligands of an adjacent complex mol-ecule, generating a chain structure along the b axis. Furthermore, an extensive series of O-H?O, N-H?O and C-H?O hydrogen-bonding inter-actions involving both the complex mol-ecules and the ethanol solvate mol-ecules generate a three-dimensional network.
dc.identifier.endpage30en_US
dc.identifier.startpage28en_US
dc.identifier.urihttps://doi.org/10.1107/S2056989016019575
dc.identifier.urihttps://hdl.handle.net/20.500.12695/1554
dc.identifier.volume73en_US
dc.indekslendigikaynakPubMed
dc.institutionauthorAtioğlu, Zeliha
dc.language.isoen
dc.relation.ispartofActa Cryst
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectcadmium
dc.subjectcrystal structure
dc.subjecthydrazone-based ligand
dc.subjecthydrogen bonding
dc.titleCrystal structure of bis-{ N'-[( E)-4-hy-droxy-benzyl-idene]pyridine-4-carbohydrazide-? N1}di-iodidocadmium methanol disolvate
dc.typeArticle

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