Crystal structure and Hirshfeld surface analysis of a new polymorph of (E)-2-(4-bromo­phen­yl)-1-[2,2-di­bromo-1-(3-nitro­phen­yl)ethen­yl]diazene

Basit Öğe Kaydı
dc.contributor.authorAtioğlu, Zeliha
dc.contributor.authorAkkurt, Mehmet
dc.contributor.authorShikhaliyev, Namiq Q.
dc.contributor.authorMammadova, N. A.
dc.contributor.authorMammadova, Naila A.
dc.contributor.authorBabayeva, Gülnara V.
dc.contributor.authorKhrustalev, Victor N.
dc.contributor.authorBhattarai, Ajaya
dc.date.accessioned2022-07-27T06:53:24Z
dc.date.available2022-07-27T06:53:24Z
dc.date.issued2022en_US
dc.departmentKapadokya Üniversitesi, Uygulamalı Bilimler Yüksekokulu, Havacılık Elektrik ve Elektroniği Bölümü
dc.description.abstractA new polymorph of the title compound, C14H8Br3N3O2, (form-2) was obtained in the same manner as the previously reported form-1 [Akkurt et al. (2022[Akkurt, M., Yıldırım, S. Ö., Shikhaliyev, N. Q., Mammadova, N. A., Niyazova, A. A., Khrustalev, V. N. & Bhattarai, A. (2022). Acta Cryst. E78, 732-736.]). Acta Cryst. E78, 732–736]. The structure of the new polymorph is stabilized by a C—H?O hydrogen bond that links mol­ecules into chains. These chains are linked by face-to-face ?–? stacking inter­actions, resulting in a layered structure. Short inter-mol­ecular Br?O contacts and van der Waals inter­actions between the layers aid in the cohesion of the crystal packing. In the previously reported form-1, C—H?Br inter­actions connect mol­ecules into zigzag chains, which are linked by C—Br?? inter­actions into layers, whereas the van der Waals inter­actions between the layers stabilize the crystal packing of form-2. Hirshfeld mol­ecular surface analysis was used to compare the inter­molecular inter­actions of the polymorphs.
dc.identifier.urihttps://doi.org/10.1107/S2056989022007113
dc.identifier.urihttps://hdl.handle.net/20.500.12695/1697
dc.institutionauthorAtioğlu, Zeliha
dc.language.isoen
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectcrystal structure
dc.subjectazo compounds
dc.subjectpolymorphism
dc.subjectC—HO interactions
dc.subjectHirshfeld surface analysis
dc.titleCrystal structure and Hirshfeld surface analysis of a new polymorph of (E)-2-(4-bromo­phen­yl)-1-[2,2-di­bromo-1-(3-nitro­phen­yl)ethen­yl]diazene
dc.typeArticle

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Küçük Resim
İsim:
yk2172.pdf
Boyut:
986.49 KB
Biçim:
Adobe Portable Document Format
Açıklama:
Makale / Article
İndir
Lisans paketi
Listeleniyor 1 - 1 / 1
[ X ]
İsim:
license.txt
Boyut:
1.44 KB
Biçim:
Item-specific license agreed upon to submission
Açıklama:
İndir

Koleksiyon

Havacılık Elektrik ve Elektroniği - Makale Koleksiyonu