Crystal structure of [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]dichlorido{2-[1-(dimethylamino)ethyl]benzylidene}ruthenium including an unknown solvate

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Küçük Resim

Tarih

2019

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Erişim Hakkı

Attribution-NonCommercial-ShareAlike 4.0 International
info:eu-repo/semantics/openAccess

Özet

The title compound, [RuCl2(C21H26N2)(C11H15N)], is an example of a new generation of N,N-dialkyl metallocomplex ruthenium catalysts with an N?Ru coordination bond as part of a six-membered chelate ring. The Ru atom has an Addison ? parameter of 0.234, which indicates a geometry inter­mediate between square-based pyramidal and trigonal–bipyramidal. The complex shows the usual trans arrangement of the two chloride ligands, with Ru—Cl bond lengths of 2.3397?(8) and 2.3476?(8)?Å, and a Cl—Ru— Cl angle of 157.47?(3)°. The crystal structure features C—H...Cl, C—H...? and ?–? stacking inter­actions. The solvent mol­ecules were found to be highly disordered and their contribution to the scattering was removed with the SQUEEZE procedure in PLATON [Spek (2015). Acta Cryst. C71, 9–18], which indicated a solvent cavity of volume 1096?Å3 containing approximately 419 electrons. These solvent mol­ecules are not considered in the given chemical formula and other crystal data.

Açıklama

TARAMASCOPUS
TARAMAWOS
TARAMAPUBMED

Anahtar Kelimeler

Crystal structure, Ruthenium catalyst, Hoveyda–Grubbs catalyst, N—Ru coordination bond, Metathesis of olefins, SQUEEZE

Kaynak

Acta Crystallographica Section E: Crystallographic Communications

WoS Q Değeri

N/A

Scopus Q Değeri

Q3

Cilt

75

Sayı

3

Künye

POLYANSKII, K. B., ALEKSEEVA, K. A., KUMANDIN, P. A., ATİOĞLU, Z., AKKURT, M., & TOZE, F. A. (2019). Crystal structure of 1 3 bis 2 4 6 trimethylphenyl imidazolidin 2 ylidene dichlorido 2 1 dimethylamino ethyl benzylidene ruthenium including an unknown solvate. Acta Crystallographica Section E: Crystallographic Communications, 75(3), 342–345.