Crystal structure of [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]dichlorido{2-[1-(dimethylamino)ethyl]benzylidene}ruthenium including an unknown solvate

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dc.authorid0000-0002-1141-5151
dc.contributor.authorPolyanskii, Kirill B.
dc.contributor.authorAlekseeva, Kseniia A.
dc.contributor.authorKumandin, Pavel A.
dc.contributor.authorAtioğlu, Zeliha
dc.contributor.authorAkkurt, Mehmet
dc.contributor.authorToze, A. A. Flavien
dc.date.accessioned2020-06-27T09:29:45Z
dc.date.available2020-06-27T09:29:45Z
dc.date.issued2019en_US
dc.departmentKapadokya Üniversitesi, Uygulamalı Bilimler Yüksekokulu, Havacılık Elektrik ve Elektroniği Bölümü
dc.descriptionTARAMASCOPUS
dc.descriptionTARAMAWOS
dc.descriptionTARAMAPUBMED
dc.description.abstractThe title compound, [RuCl2(C21H26N2)(C11H15N)], is an example of a new generation of N,N-dialkyl metallocomplex ruthenium catalysts with an N?Ru coordination bond as part of a six-membered chelate ring. The Ru atom has an Addison ? parameter of 0.234, which indicates a geometry inter­mediate between square-based pyramidal and trigonal–bipyramidal. The complex shows the usual trans arrangement of the two chloride ligands, with Ru—Cl bond lengths of 2.3397?(8) and 2.3476?(8)?Å, and a Cl—Ru— Cl angle of 157.47?(3)°. The crystal structure features C—H...Cl, C—H...? and ?–? stacking inter­actions. The solvent mol­ecules were found to be highly disordered and their contribution to the scattering was removed with the SQUEEZE procedure in PLATON [Spek (2015). Acta Cryst. C71, 9–18], which indicated a solvent cavity of volume 1096?Å3 containing approximately 419 electrons. These solvent mol­ecules are not considered in the given chemical formula and other crystal data.
dc.description.sponsorshipRussian Science Foundation (project No. 18–13-00456)
dc.identifier.citationPOLYANSKII, K. B., ALEKSEEVA, K. A., KUMANDIN, P. A., ATİOĞLU, Z., AKKURT, M., & TOZE, F. A. (2019). Crystal structure of 1 3 bis 2 4 6 trimethylphenyl imidazolidin 2 ylidene dichlorido 2 1 dimethylamino ethyl benzylidene ruthenium including an unknown solvate. Acta Crystallographica Section E: Crystallographic Communications, 75(3), 342–345.
dc.identifier.doi10.1107/S2056989019001725
dc.identifier.endpage345en_US
dc.identifier.issn2056-9890
dc.identifier.issue3en_US
dc.identifier.scopusqualityQ3
dc.identifier.startpage342en_US
dc.identifier.urihttps://hdl.handle.net/20.500.12695/562
dc.identifier.urihttps://doi.org/10.1107/S2056989019001725
dc.identifier.volume75en_US
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Sceince
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.institutionauthorAtioğlu, Zeliha
dc.language.isoen
dc.relation.ispartofActa Crystallographica Section E: Crystallographic Communications
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsAttribution-NonCommercial-ShareAlike 4.0 International*
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.rights.urihttps://creativecommons.org/licenses/by-nc-sa/4.0/*
dc.subjectCrystal structure
dc.subjectRuthenium catalyst
dc.subjectHoveyda–Grubbs catalyst
dc.subjectN—Ru coordination bond
dc.subjectMetathesis of olefins
dc.subjectSQUEEZE
dc.titleCrystal structure of [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]dichlorido{2-[1-(dimethylamino)ethyl]benzylidene}ruthenium including an unknown solvate
dc.typeArticle

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