Poly(styrene)-co-2-vinylpyridine copolymer as a novel solid-phase adsorbent for determination of manganese and zinc in foods and vegetables by FAAS
Yükleniyor...
Tarih
2020
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elseiver
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
he aim of this study is to extract zinc and manganese from foods and vegetables using an amphiphilic copo lymer adsorbent, poly(styrene)-co-2-vinylpyridine which was synthesized via reversible addition fragmentation chain transfer (RAFT) polymerization from styrene and 2-vinyl pyridine in the presence of a trithiocarbonate and 2,2?-azo-bis isobutyro nitrile (AIBN) in toluene solution under argon at 80 °C. Fourier Transform Infrared (FTIR) and proton nuclear magnetic resonance (1 H NMR) spectroscopy were used in the characterization of the ob tained copolymer. Under the optimum conditions, several validation variables such as uncertainty measurement, selectivity, robustness, precisions, matrix effects and accuracy were investigated. Taking an adsorption time of 15 min, detection limits of 0.04 ?g L ?1 and 0.2 ?g L ?1 and 7.9 ?g L?1 and enrichment factors of 145 and 110 were obtained for Mn(II) and Zn(II), respectively. The method was successfully applied to the analysis of Mn(II) and Zn(II) in foods and vegetables.
Açıklama
TARAMAPUBMED
TARAMASCOPUS
TARAMASCOPUS
Anahtar Kelimeler
Zinc, Manganese, Food, Vegetable, Amphiphilic copolymer, Solid-phase microextraction
Kaynak
Food Chemistry
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
Sayı
333
Künye
HAZER, B., TÜZEN, M., ELİK, A., ŞİMŞEK, S., & ALTUNAY, N. (2020). Poly styrene -co-2-vinylpyridine copolymer as a novel solid-phase adsorbent for determination of manganese and zinc in foods and vegetables by FAAS. Food Chemistry, 333, 0–0.
