Crystal structure and Hirshfeld surface analysis of (2Z)-N, N-dimethyl-2-(pentafluorophenyl)-2-(2-phenylhydrazin-1-ylidene) acetamide
Yükleniyor...
Dosyalar
Tarih
2021
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
In the title compound, C16H12F5N3O, the dihedral angle between the aromatic rings is 31.84?(8)°. In the crystal, the molecules are linked into dimers possessing crystallographic twofold symmetry by pairwise N—H?O hydrogen bonds and weak C—H?O hydrogen bonds and aromatic ?–? stacking interactions link the dimers into a three-dimensional network. A Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from F?H/H?F (41.1%), H?H (21.8%), C?H/H?C (9.7%) C?C (7.1%) and O?H/H?O (7.1%) contacts. The contribution of some disordered solvent to the scattering was removed using the SQUEEZE routine [Spek (2015). Acta Cryst. C71, 9–18] in PLATON. The solvent contribution was not included in the reported molecular weight and density.
Açıklama
TARAMAWOS
TARAMASCOPUS
TARAMASCOPUS
Anahtar Kelimeler
Crystal structure, Fluorine, Hydrogen bonds, Stacking interactions, SQUEEZE, Hirshfeld surface analysis
Kaynak
Acta Cryst
WoS Q Değeri
N/A
Scopus Q Değeri
N/A
Cilt
Sayı
E77
